Trichloroisocyanuric/TEMPO Oxidation of Alcohols under Mild Conditions: A Close Investigation
Articolo
Data di Pubblicazione:
2003
Citazione:
Trichloroisocyanuric/TEMPO Oxidation of
Alcohols under Mild Conditions: A Close
Investigation / DE LUCA, Lidia Vera Giovanna; Giacomelli, Giampaolo; Masala, M.; Porcheddu, Andrea. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 68:12(2003), pp. 4999-5001. [10.1021/jo034276b]
Abstract:
Efficient oxidation of primary alcohols to the
corresponding carboxylic acids can be carried out at room
temperature and in acetone/water, using trichloroisocyanuric
acid (TCCA) in the presence of catalytic TEMPO. The mild
conditions of this procedure and the total absence of any
transition metal make this reaction suitable for safe laboratory
use. A possible mechanism is presented and discussed.
corresponding carboxylic acids can be carried out at room
temperature and in acetone/water, using trichloroisocyanuric
acid (TCCA) in the presence of catalytic TEMPO. The mild
conditions of this procedure and the total absence of any
transition metal make this reaction suitable for safe laboratory
use. A possible mechanism is presented and discussed.
Tipologia CRIS:
1.1 Articolo in rivista
Elenco autori:
DE LUCA, Lidia Vera Giovanna; Giacomelli, Giampaolo; Masala, M.; Porcheddu, Andrea
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