A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system
Articolo
Data di Pubblicazione:
2016
Citazione:
A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system / Santoru, A., Garroni, S., Pistidda, C., Milanese, C., Girella, A., Marini, A., Masolo, E., Valentoni, A., Bergemann, N., Le, T.T., Cao, H., Haase, D., Balmes, O., Taube, K., Mulas, G.R.C.E., Enzo, S., Klassen, T., Dornheim, M.. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9084. - 18:5(2016), pp. 3910-3920. [10.1039/c5cp06963g]
Abstract:
New insights into the reaction pathways of different potassium/magnesium amide–hydride based sys- tems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K–N–H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide–hydride anionic exchange is proposed.
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
Physics and Astronomy (all); Physical and Theoretical Chemistry
Elenco autori:
Santoru, A; Garroni, Sebastiano; Pistidda, C.; Milanese, C.; Girella, A.; Marini, A.; Masolo, Elisabetta; Valentoni, A.; Bergemann, N.; Le, T. T.; Cao, H.; Haase, D.; Balmes, O.; Taube, K.; Mulas, Gabriele Raimondo Celestino Ettore; Enzo, Stefano; Klassen, T.; Dornheim, M.
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