On the relationship between structure and reaction rate in olefin ring-closing metathesis
Academic Article
Publication Date:
2010
Short description:
On the relationship between structure and reaction rate in olefin ring-closing metathesis / Ashworth, I.W., Carboni, D., Hillier, I.H., Nelson, D.J., Percy, J.M., Rinaudo, G., Vincent, M.A.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 46:38(2010), pp. 7145-7147. [10.1039/c0cc02440f]
abstract:
In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex. © 2010 The Royal Society of Chemistry.
Iris type:
1.1 Articolo in rivista
Keywords:
Alkenes; Cyclization; Cyclohexenes; Cyclopentanes; Kinetics; Molecular Structure; 2506; Materials Chemistry2506 Metals and Alloys; Surfaces, Coatings and Films; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Catalysis; Chemistry (all)
List of contributors:
Ashworth, Ian W; Carboni, Davide; Hillier, Ian H.; Nelson, David J.; Percy, Jonathan M.; Rinaudo, Giuseppe; Vincent, Mark A.
Published in: