Publication Date:
2016
Short description:
KNH2- KH: a metal amide - hydride solid solution / Santoru, A., Pistidda, C., Sørby, M.H., Chierotti, M.R., Garroni, S., Pinatel, E., Karimi, F., Cao, H., Bergemann, N., Le, T.T., Puszkiel, J., Gobetto, R., Baricco, M., Hauback, B.C., Klassen, T., Dornheim, M.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (2016). [10.1039/C6CC05777B]
abstract:
We report for the first time the formation of a metal amidehydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
Iris type:
1.1 Articolo in rivista
Keywords:
hydrogen storage, amides,
List of contributors:
Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus Helgerud; Chierotti, Michele Remo; Garroni, Sebastiano; Pinatel, Eugenio; Karimi, Fahim; Cao, Hujun; Bergemann, Nils; Le, Thi Thu; Puszkiel, Julián; Gobetto, Roberto; Baricco, Marcello; Hauback, Bjorn C.; Klassen, Thomas; Dornheim, Martin
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