Regioselective Reductive Alkylation of 3,4,5-Trimethoxybenzalbehyde Dimethyl Acetal: a New Synthesis of 4-Alkyl-3,5-Dimethoxybenzaldehydes and 2,5-Dialkyl-1,3-Dimethoxybenzenes
Academic Article
Publication Date:
1990
Short description:
Regioselective Reductive Alkylation of 3,4,5-Trimethoxybenzalbehyde Dimethyl Acetal: a New Synthesis of 4-Alkyl-3,5-Dimethoxybenzaldehydes and 2,5-Dialkyl-1,3-Dimethoxybenzenes / Azzena, Ugo Gavino; S., Cossu; T., Denurra; G., Melloni; A. M., Piroddi. - In: SYNTHESIS. - ISSN 0039-7881. - (1990), pp. 313-314.
abstract:
the regioselective replacement of the 4-methoxy group of 3,4,5-trimethoxybenzaldehyde dimethyl acetal by an alkyl group under reductive SET conditions has been employed as a key step in the synthesis of 2,5-dialkylresorcinols
Iris type:
1.1 Articolo in rivista
Keywords:
2,5-dialkylresorcinols; electron transfer; reductive metalation
List of contributors:
Azzena, Ugo Gavino; S., Cossu; T., Denurra; G., Melloni; A. M., Piroddi
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