Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane
Academic Article
Publication Date:
1992
Short description:
Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane / W., A., Azzena, U.G., F., P., K., H., W., M.. - In: CHEMISCHE BERICHTE-RECUEIL. - ISSN 0009-2940. - 125:(1992), pp. 1409-1411. [10.1002/cber.19921250618]
abstract:
The reaction of ferriohydridosilanes Cp(CO)(L)Fe - SiR2H (R = Me, t-Bu, Ph, o-Tolyl; L = CO, Ph3P) 1a-e with dimethyldioxirane (as an acetone solution) leads directly to the corresponding ferriosilanols Cp(CO)(L)Fe-SiR2OH 2a-e in moderate to excellent yields
Iris type:
1.1 Articolo in rivista
Keywords:
ferriosilanes; ferriosilanols; dimethyldioxirane
List of contributors:
W., Adam; Azzena, Ugo Gavino; F., Prechtl; K., Hindahl; W., Malisch
Published in: