Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta(2)-CH2=CHPh)][PF6] (bipy(ip)=6-isopropyl-2,2 '-bipyridine)
Academic Article
Publication Date:
2004
Short description:
Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta(2)-CH2=CHPh)][PF6] (bipy(ip)=6-isopropyl-2,2 '-bipyridine) / Cinellu, M.A., Minghetti, G., Stoccoro, S., Zucca, A., Manassero, M.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 14(2004), pp. 1618-1619. [10.1039/b404890c]
abstract:
Gold alkene complexes [Au(bipy(R))(eta(2)-alkene)][PF6] (bipy(R)=6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au-2(bipy(R))(2)(mu-O)(2)][PF6](2) with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta(2)-CH2=CHPh)][PF6] (bipy(ip)=6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis.
Iris type:
1.1 Articolo in rivista
Keywords:
gold alkene complexes; nitrogen ligands; X-ray diffraction
List of contributors:
Cinellu, Maria Agostina; Minghetti, G.; Stoccoro, Sergio; Zucca, Antonio; Manassero, M.
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