Publication Date:
2006
Short description:
Reducing Properties of 1,2-Disodium-1,2-diarylethanes / Azzena, U.G., Mario, P., Giovanna, D., Simona, M., Emanuela, A.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 47:(2006), pp. 1055-1058.
abstract:
Abstract—1,2-Diphenyl- and 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane efficiently dehalogenate vic-dibromoderivatives, affording
the corresponding alkenes. The reaction proceeds rapidly, under mild conditions and is tolerant of a variety of functional groups
(alcohol, carboxylic acid, ester and amide). This procedure was successfully extended to similar vic-disubstituted compounds
the corresponding alkenes. The reaction proceeds rapidly, under mild conditions and is tolerant of a variety of functional groups
(alcohol, carboxylic acid, ester and amide). This procedure was successfully extended to similar vic-disubstituted compounds
Iris type:
1.1 Articolo in rivista
Keywords:
Alkali metals; elimination; dianions
List of contributors:
Azzena, Ugo Gavino; Mario, Pittalis; Giovanna, Dettori; Simona, Madeddu; Emanuela, Azara
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