Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization
Academic Article
Publication Date:
2001
Short description:
Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization / Stoccoro, S., Minghetti, G., Cinellu, M.A., Zucca, A., Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 20:19(2001), pp. 4111-4113. [10.1021/om010278f]
abstract:
In the ethene/CO copolymerization catalyzed
by palladium derivatives, species arising from ethene
insertion into the palladium-acyl bond have been shown
to play a key role. We report here the synthesis, spectroscopic
characterization, and X-ray structure of the
complex [Pd{CH2CH2C(O)Me}(HL)][BAr¢4] (HL ) 6-Me-
2,2¢-bipyridine, Ar¢ ) 3,5-(CF3)2C6H3), 4, the first one
having an ancillary N,N ligand to be characterized in
the solid state.
by palladium derivatives, species arising from ethene
insertion into the palladium-acyl bond have been shown
to play a key role. We report here the synthesis, spectroscopic
characterization, and X-ray structure of the
complex [Pd{CH2CH2C(O)Me}(HL)][BAr¢4] (HL ) 6-Me-
2,2¢-bipyridine, Ar¢ ) 3,5-(CF3)2C6H3), 4, the first one
having an ancillary N,N ligand to be characterized in
the solid state.
Iris type:
1.1 Articolo in rivista
Keywords:
copolymerization; catalysis; palladium complexes
List of contributors:
Stoccoro, S; Minghetti, G; Cinellu, Maria Agostina; Zucca, Antonio; Manassero, M.
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