The Effect of Topologically Controlled Coulombic Interactions on the Regioselectivity of the Reductive Cleavage of Alkyl Phenyl Ethers
Academic Article
Publication Date:
1996
Short description:
The Effect of Topologically Controlled Coulombic Interactions on the Regioselectivity of the Reductive Cleavage of Alkyl Phenyl Ethers / Azzena, U.G., F., C., P., F., I., G., Pisano, L., J., M., G., M.. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - 12(1996), pp. 2563-2566. [10.1039/p29960002563]
abstract:
The importance of electrostatic effects in the chemical evolution of charged intermediates of the radical anion type is demonstrated, Thus, the regioselectivity of the electron transfer-induced reductive cleavage of alkyl 2,6-diphenylphenyl ethers and alkyl 2,6-dimethoxyphenyl ethers is completely reversed when a positive charge is placed in a controlled manner near the alkyl ether bond
Iris type:
1.1 Articolo in rivista
Keywords:
alkyl phenyl ethers; electron transfer; coulombic interactions
List of contributors:
Azzena, Ugo Gavino; F., Casado; P., Fois; I., Gallardo; Pisano, Luisa; J., Marquet; G., Melloni
Published in: