Multiple C-H bond activation. 3-fold deprotonated 6-phenyl-2,2’-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives
Academic Article
Publication Date:
2002
Short description:
Multiple C-H bond activation. 3-fold deprotonated 6-phenyl-2,2’-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives / Zucca, A., Doppiu, A., Cinellu, M.A., Stoccoro, S., Minghetti, G., Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 21:5(2002), pp. 783-785. [10.1021/om010913h]
abstract:
Unusual platinum(II) trimetalated derivatives
have been synthesized and characterized by reaction
of cis-[Pt(R)2(DMSO)2] (R ) Me, Ph) and 6-phenyl-2,2¢-
bipyridine. The behavior of the substituted 2,2¢-bipyridine
as a threefold-deprotonated ligand is unprecedented.
have been synthesized and characterized by reaction
of cis-[Pt(R)2(DMSO)2] (R ) Me, Ph) and 6-phenyl-2,2¢-
bipyridine. The behavior of the substituted 2,2¢-bipyridine
as a threefold-deprotonated ligand is unprecedented.
Iris type:
1.1 Articolo in rivista
Keywords:
C-H bond activation; platinum complexes; cyclometallation
List of contributors:
Zucca, Antonio; Doppiu, A; Cinellu, Maria Agostina; Stoccoro, Sergio; Minghetti, G; Manassero, M.
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