Reactivity of Arylic Carbanions Generated by Reductive Cleavage of C-N Bond of N,N-Dimethylanilines
Articolo
Data di Pubblicazione:
2003
Citazione:
Reactivity of Arylic Carbanions Generated by Reductive Cleavage of C-N Bond of N,N-Dimethylanilines / Azzena, Ugo Gavino; Cattari, M.; Melloni, G.; Pisano, Luisa. - In: SYNTHESIS. - ISSN 0039-7881. - 18(2003), pp. 2811-2814. [10.1055/s-2003-42481]
Abstract:
Phenyl-substituted N,N-dimethylanilines, synthesized by Suzuki coupling reactions in good yields, are transformed to their corresponding arylic carbanions by reductive C-N cleavage with lithium at room temperature. These carbanions react with various electrophiles affording the corresponding ipso-substituted products with absolute regioselectivity
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
aryllithium; reduction; deamination
Elenco autori:
Azzena, Ugo Gavino; Cattari, M.; Melloni, G.; Pisano, Luisa
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